2-Methylcyclohexanone to 2,2- and 2,6-dimethylcyclohexanone

Autor:

DMacks (diskuse)

Shortlink:

https://czwiki.cz/b/c0dd5

Zdroj:

Wikimedia Commons

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3263 x 1356 Pixel (214850 Bytes)

Popis:

Skeletal structures for the reaction of 2-methylcyclohexanone with various bases (potassium bis(trimethylsilyl)amide (KHMDS) or potassium hydride) followed by triethylborane to form two different enolates. A subsequent reaction with iodomethane gives different methylated structural isomers depending on the enolate position.)

Licence:

Public domain

Credit:

Vlastní dílo based on en:2-Methylcyclohexanone to 2,2- and 2,6-dimethylcyclohexanone.jpg created and asserted as {{PD-chem}} by en:User:EdChem, which they based on "Enoxytriethylborates and Enoxydiethylboranes" in Crich, David , ed. (2008) Reagents for Radical and Radical Ion Chemistry, Handbook of Reagents for Organic Synthesis, 11, John Wiley & Sons ISBN: 9780470065365.

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